(2,9-Dimethyl-1,10-phenanthroline-κ2 N,N′)(4-hydroxy­benzoato-κ2 O,O′)(nitrato-κO)copper(II)

نویسندگان

  • Cui-Ping Zhai
  • Feng-Mei Yan
  • Pei-Zheng Zhao
چکیده

In the title compound, [Cu(C(7)H(5)O(3))(NO(3))(C(14)H(12)N(2))], the Cu(II) ion is five-coordinated in a slightly distorted square-pyramidal geometry by one O atom of a nitrate anion, two O atoms of a 4-hydroxy-benzoate anion, and two N atoms from a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand. In the crystal structure, inversion-related mol-ecules are linked into dimers by O-H⋯O hydrogen bonds. The packing is further stabilized by π-π inter-actions involving the benzene rings of the dmphen and hydroxy-benzoate units, with centroid-centroid distances of 3.4930 (14) or 3.5727 (14) Å.

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(2,9-Dimethyl-1,10-phenanthroline-κ2 N,N′)bis­(2-hydroxy­benzoato-κO)copper(II)

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A reference in the paper by Xuan & Zhao [Acta Cryst. (2007), E63, m2678] is replaced.[This corrects the article DOI: 10.1107/S1600536807045941.].

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008